Chemistry Learner

It's all about Chemistry

Nitrogen

What is Nitrogen

Nitrogen (pronounced as Nye-treh-gen) is a chemical element, existing in the form of a colorless diatomic gas. Denoted by the chemical symbol N, it belongs to the family of nonmetals. It is the fifth most abundant element in the earth’s crust, represented by the molecular formula N2 [1, 2]. There are 12 isotopes of nitrogen with masses ranging from 11 to 19 of which only N-14 and N-15 occur naturally [3].

Where is Nitrogen Found

In the earth’s atmosphere, it constitutes about 78% of the air that is estimated to be around 4000 trillion tons. It is extracted from the liquefied air through fractional distillation [1, 2].

Nitrogen

History

Origin of its Name: It is derived from the Greek words ‘nitron’ and ‘genes’ that mean nitre forming. [1].

Who Discovered it: Daniel Rutherford [1]

When, Where, and How was it Discovered

It was first obtained during the 1760’s by two English scientists Henry Cavendish and Joseph Priestley while attempting to separate oxygen from the air. However, they were unable to confirm the presence of a new gaseous element in the atmosphere. It was only in September 1772 at Edinburgh, Scotland when Rutherford named it nitrogen after a thorough analysis [1].

Nitrogen Element

Classification, Properties, and Characteristics of Nitrogen

General Properties

Relative/Average atomic mass 14.007 [1]
Atomic mass/weight 14.007 atomic mass units [5]
Molar mass/Molecular weight 28.014 g/mol [4]
Mass number 14

Physical Properties

Color/physical appearance Colorless [1]
Odor Odorless [4]
Melting point/freezing point -210°C (-346°F) [1]
Boiling point -195.795°C (-320.431°F)  [1]
Density 0.001145 g/cm3 [1]
Standard/Physical state of matter at normal room temperature (solid/liquid/gas) Gas [1]
Electrical conductivity Unknown [3]
Thermal conductivity 0.02583 Wm-1K-1 [4]

Chemical Properties

Flammability Non-flammable [4]
Oxidation states (numbers)  5, 4, 3, 2,-3 [1]

Nitrogen Lewis Dot Structure

Atomic Data of Nitrogen (Element 14)

Valence electrons 5 [6]
Electron configuration (noble gas configuration) [He] 2s22p3[1]
Atomic structure [3]
– Number of Electrons 7
– Number of Neutrons 7
– Number of Protons 7
Radius of atom
– Atomic radius 1.55 Å [1]
– Covalent radius 0.71 Å [1]
Electronegativity 3.04 [3]
Ion charge -3 [7]
Ionization energy [1]

(kJmol-1)

1st 2nd 3rd 4th 5th 6th 7th
1402.328 2856.092 4578.156 7475.057 9444.969 53266.97 33603.91

Nitrogen Atomic Structure (Bohr Model)

What are the Common Uses of Nitrogen

  • Nitrogen-filled tires have more stable pressure than the air-filled ones, minimizing the possibility of a leak [1].
  • It is used in annealing stainless steel to reduce stress and improve its overall function [1].
  • Being an inert nonmetal, it is used to shield semiconductor devices like light-emitting diodes and transistors [1, 2].
  • Liquid nitrogen is an effective cryogen used in medical spray equipment to remove warts, benign tumors, and malignant lesions as well as to treat other skin-related problems [8]. It is also used as a refrigerant to store donor organs, eggs, sperms, and other body cells for medical purpose and research studies. Additionally, it helps in storing food for a longer time [1].
  • Organic nitrogen is an essential chemical constituent in fertilizers, nylon, dyes, nitric acid, and explosives [1].
  • Nitrogen plastic welders are used in repairing plastic components of automobiles by eliminating oxygen [9].
  • Nitrogen mustard, a type of mustard gas comprising of nitrogen, are used as chemotherapeutic agents in the treatment of cancer [10].

Is the Element Toxic

Inhalation of high levels of N2 may lead to suffocation, weakness, and unconsciousness [4]. Deep-sea divers are prone to a condition called narcosis marked by symptoms like hallucination, disorientation, loss of concentration, and short-term memory loss as a result of increased nitrogen pressure in the blood [11]. If the liquid form of the nonmetal comes in contact with the skin and eyes, it may cause some dangerous effects like frostbite, pain, and burns [4].

Liquid Nitrogen

Interesting Facts

  • It is a major constituent of proteins and nucleic acids (DNA and RNA) in the body of most living organisms [4].
  • During the Egyptian civilization, it used to be obtained by heating a mixture of dung, salt, and urine [1].
  • Nitrogen is sometimes called ‘dephlogisticated’ or ‘burnt’ since once all the oxygen is taken out from the air it only comprises of the former [12].

Nitrogen Cost

Since it is sold as cylinders, a standard 50-liter one would cost you around $150 while the price of liquid nitrogen varies somewhere between $0.50 and $0.60 per gallon.

References

  1. http://www.rsc.org/periodic-table/element/7/nitrogen
  2. https://education.jlab.org/itselemental/ele007.html
  3. https://www.chemicool.com/elements/nitrogen.html
  4. https://pubchem.ncbi.nlm.nih.gov/compound/Nitrogen#section=Top
  5. https://hobart.k12.in.us/ksms/PeriodicTable/nitrogen.htm
  6. https://chem.libretexts.org/Textbook_Maps/Inorganic_Chemistry/Supplemental_Modules_(Inorganic_Chemistry)/Descriptive_Chemistry/Elements_Organized_by_Block/2_p-Block_Elements/Group_15%3A_The_Nitrogen_Family/Z%3D007_Chemistry_of_Nitrogen_(Z%3D7)
  7. https://opencurriculum.org/9436/chemical-properties-of-nitrogen/
  8. https://www.aafp.org/afp/2004/0515/p2365.html
  9. https://rts.i-car.com/collision-repair-news/nitrogen-hot-air-welding.html
  10. http://cutaneouslymphoma.stanford.edu/community/mustargen.html
  11. https://www.thoughtco.com/what-is-nitrogen-narcosis-2963052
  12. https://www.thoughtco.com/nitrogen-facts-606568

Leave a Reply

Your email address will not be published. Required fields are marked *

Trending Topics