Promethium
What is Promethium
Promethium (pronounced as pro-MEE-thee-em) is a radioactive metal with the chemical symbol Pm, belonging to the family of lanthanides as it does not exist naturally in the earth’s crust [1, 3]. It has twenty-nine isotopes with mass numbers ranging from 130 to 158 of which the most stable one is promethium-145 having a half-life of 17.7 years [2, 4].
History
Origin of its Name: Promethium got its name from Prometheus, the Greek mythological titan who gifted fire to the human race after stealing it from the Gods [1].
Who Discovered it: Jacob .A. Marinsky, Charles D. Coryell, and Lawrence E. Glendenin were its discoverers.
When, Where, and How was it Discovered
Several attempts were believed to be made to find the existence of the new element as the well-known Czech chemist, Bohuslav Brauner speculated the possibility of another element between neodymium and samarium. In 1939, at the University of California, a 60-inch cyclotron was used for the same purpose. However, nothing was proved [1].
It was only in 1945 when Marinsky, Coryell, and Glendenin at the Oak Ridge, Tennessee used ion-exchange chromatography to separate the new element from the fission products of uranium fuel from a nuclear reactor [1].
Promethium Identification |
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Atomic number | 61 [1] | ||
CAS number | 7440-12-2 [1] | ||
Position in the periodic table [1] | Group | Period | Block |
Lanthanides | 6 | f |
Properties and Characteristics of Promethium
General Properties |
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Relative atomic mass | [245] [1] | |
Atomic mass | 245 atomic mass units [5] | |
Physical Properties |
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Color/appearance | Unknown [1] | |
Melting point/freezing point | 1042°C (1908°F) [1] | |
Boiling point | 3000°C, 5432°C [1] | |
Density | Unknown [1] | |
State at normal room temperature (solid/liquid/gas) | Solid [1] | |
Electrical conductivity | 2×106 Sm-1[1] | |
Chemical Properties |
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Oxidation state/Oxidation number | (+2) +3 [1] |
Atomic Data of Promethium (Element 61)
Valence electrons | 3 [5] | ||||||
Electron configuration (noble gas configuration) | [Xe] 4f56s2 [1] | ||||||
Quantum numbers [6] | |||||||
– n | 4 | ||||||
– ℓ | 3 | ||||||
– m ℓ | 1 | ||||||
– m s | +1/2 | ||||||
Atomic structure [3] | |||||||
– Number of Electrons | 61 | ||||||
– Number of Neutrons | 84 | ||||||
– Number of Protons | 61 | ||||||
Radius of atom | |||||||
– Atomic Radius | 2.38 Å [1] | ||||||
– Covalent Radius | 1.86 Å [1] | ||||||
Ionization energy [1]
(kJmol-1) |
1st | 2nd | 3rd | 4th | 5th | 6th | 7th |
538.581 | 1051.7 | 2151.6 | 3965.5 | – | – | – |
Uses of Promethium
The beta particles generated as a result of radioactive decay of promethium are used to make phosphor give off light that when converted into electricity by a solar cell provides power to radios, pacemakers, and guided missiles [1, 2].
Interesting Facts
- It can be obtained from the byproducts of uranium fission [2].
- Promethium-147 is produced by bombarding neodymium-146 with neutrons through a chain of decays [2].
- The radioactive metal is believed to be present in the star of the Andromeda constellation [1].
Promethium Cost
Since the utility of the metal is based on its radioactive decay, it’s estimated to cost $ 0.5 per Curie (3.7 x 1010 decays per second).
- References
- http://www.rsc.org/periodic-table/element/61/promethium
- https://education.jlab.org/itselemental/ele061.html
- https://pubchem.ncbi.nlm.nih.gov/compound/promethium#section=Computed-Properties
- https://www.chemicool.com/elements/promethium.html
- http://periodictable.com/Properties/A/Valence.al.html
- http://chemistry-reference.com/q_elements.asp?Symbol=Pm&language=en